Abstract

Abstract The SO2 pyrolysis was measured behind reflected shock waves under low SO2 concentrations. A typical induction zone was observed in the decomposition process. It was found that the overall rate constants after the induction zone were in good agreement with the values for the primary reaction obtained by the following investigators: Just and Rimpel, Kiefer, and Grillo et al. This implies that, even in highly diluted mixtures at low pressures, the kinetics of the SO2 decomposition is complicated.

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