Abstract
Liesegang phenomena are explained on the basis of simple diffusion equation considering only the diffusion of the outer electrolyte. Using this theory the time and spacing laws have been established. Two new relations have been derived, one relating the diffusion depth and the width of the rings, and another relating the concentration of the outer electrolyte, depth of diffusion and time of formation of the rings. All these relations have been tested using experimental results. The agreement between the observed and calculated values suggests the validity of the assumption that for a particular medium,Liesegang phenomena are controlled mainly by the distribution of the outer electrolyte in the medium.
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