Abstract
The theory of fluids based on the radial distribution function, g(r) , is related to the direct correlation function, f(r) , of scattering theory. The simplest form of the Born-Green theory is shown to be intimately related to the first approximation to f(r) . The second approximation to f(r) is considered in detail, and shown to effect a considerable improvement on earlier theories. It leads to a critical point at which p/ρkT =⅓. Fournet’s application of the Born-Green theory to X-ray scattering by fluids is shown to be correct only to the first power in the density ρ. The terms in ρ and ρ 2 are considered in detail for the case of hard spheres.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.