Abstract
Three electronic transitions in the singlet manifold of the zirconium sulphide (ZrS) molecule have been rotationally analyzed. They are the B1Π–X1Σ+, C1Σ+–X1Σ+, and E1Σ+–X1Σ+systems with (0,0) band heads at 924.60, 731.51, and 494.47 nm, respectively. The ground state X1Σ+has an equilibrium bond distance of 2.15661(4) Å. Perturbations in the B1Π and C1Σ+states are discussed.
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