Abstract

The organic magnetoresistive (OMAR) effect has been observed in many different organic semiconductors, whereas a corresponding effect has not been reported for inorganic ones. What property makes organics behave so differently regarding magnetotransport? By studying C 60 devices using several different electrode materials we show that C 60, unlike many other organic semiconductors, does not exhibit any intrinsic OMAR effect. However, we find that as soon as the carriers in C 60 are brought in proximity with hydrogen-containing compounds, either in the form of a polymeric electrode, or side-chain substituents, a weak OMAR effect is observed. This shows that hydrogen is crucial for the observation of OMAR.

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