Abstract

Abstract. Ocean observations are analysed in the framework of Collaborative Research Center 754 (SFB 754) "Climate-Biogeochemistry Interactions in the Tropical Ocean" to study (1) the structure of tropical oxygen minimum zones (OMZs), (2) the processes that contribute to the oxygen budget, and (3) long-term changes in the oxygen distribution. The OMZ of the eastern tropical North Atlantic (ETNA), located between the well-ventilated subtropical gyre and the equatorial oxygen maximum, is composed of a deep OMZ at about 400 m in depth with its core region centred at about 20° W, 10° N and a shallow OMZ at about 100 m in depth, with the lowest oxygen concentrations in proximity to the coastal upwelling region off Mauritania and Senegal. The oxygen budget of the deep OMZ is given by oxygen consumption mainly balanced by the oxygen supply due to meridional eddy fluxes (about 60%) and vertical mixing (about 20%, locally up to 30%). Advection by zonal jets is crucial for the establishment of the equatorial oxygen maximum. In the latitude range of the deep OMZ, it dominates the oxygen supply in the upper 300 to 400 m and generates the intermediate oxygen maximum between deep and shallow OMZs. Water mass ages from transient tracers indicate substantially older water masses in the core of the deep OMZ (about 120–180 years) compared to regions north and south of it. The deoxygenation of the ETNA OMZ during recent decades suggests a substantial imbalance in the oxygen budget: about 10% of the oxygen consumption during that period was not balanced by ventilation. Long-term oxygen observations show variability on interannual, decadal and multidecadal timescales that can partly be attributed to circulation changes. In comparison to the ETNA OMZ, the eastern tropical South Pacific OMZ shows a similar structure, including an equatorial oxygen maximum driven by zonal advection but overall much lower oxygen concentrations approaching zero in extended regions. As the shape of the OMZs is set by ocean circulation, the widespread misrepresentation of the intermediate circulation in ocean circulation models substantially contributes to their oxygen bias, which might have significant impacts on predictions of future oxygen levels.

Highlights

  • The oceanic oxygen distribution is generally characterised by slightly supersaturated oxygen levels in the surface layer, an intermediate oxygen minimum, and higher oxygen levels at depth

  • apparent oxygen utilisation rate (AOUR) calculated using the tracer age follows an exponential decay with depth, at least for oceanic regions dominated by advection (Riley, 1951; Jenkins, 1982, 1998; Karstensen et al, 2008; Martz et al, 2008; Stanley et al, 2012)

  • Model runs indicate a control of decadal and bidecadal climate variability in the tropical Pacific by the off-equatorial South Pacific Ocean triggered by changes in wind stress curl in the South Pacific extratropics (Tatebe et al, 2013) as an additional mechanism for oxygen variability

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Summary

Introduction

The oceanic oxygen distribution is generally characterised by slightly supersaturated oxygen levels in the surface layer, an intermediate oxygen minimum, and higher oxygen levels at depth. North of the ETNA OMZ, the North Equatorial Current (NEC) flows southwestward along the Cape Verde Frontal Zone It transports oxygen-rich Central Water (CW) formed by subduction in the subtropics as well as intermediate water masses in the deeper layers that have their origin mainly in the Labrador Sea and the Mediterranean outflow. The poorly ventilated OMZ, the even older AAIW (σθ = 27.3 kg m−3) with ventilation times in excess of 500 years is found (close to the detection limit of the CFCs, and difficult to quantify accurately), this water mass has a high oxygen concentration At this density layer, the area south of 5◦ N is significantly better ventilated than north of 5◦ N (Schneider et al, 2012). The remaining oxygen variance in regions of weak mean flow surrounding the ETNA OMZ might be associated with processes responsible for the vertical and lateral mixing that is discussed in the following subsections

Vertical mixing
Lateral mixing
Advection
Upwelling and circulation
Benthic oxygen uptake
Diapycnal oxygen fluxes at the continental margin
The large-scale distribution
Mesoscale processes
Oxygen budgets
Trends in oxygen
Findings
Summary and discussion
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