Abstract
AbstractIn the action of acetic anhydride on picolyl lithium (I) the by‐product 1,3‐bis‐(2‐pyridyl)‐2‐methylpropanol‐2 (III) is formed in addition to α‐picolylmethylketone (II); in the action of acetyl chloride on I it depends upon the conditions of the experiment whether the main product will be II or III. In the action of benzoic anhydride on I α‐picolylphenylketone (IV) is formed and a small amount of (2‐pyridyl)‐dibenzoylmethane (V). According to the conditions of the experiment the action of benzoylchloride on I gives mainly IV or a base containing no oxygen: 1,3‐bis‐(2‐pyridyl)‐2‐phenylpropene (IX). In the action of phenyl lithium and benzoic anhydride on lutidine 6‐(2‐picolyl)‐dibenzoylmethane (XVII) is formed.
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