Abstract
The complex trans-[Ru(NH 3) 4P(OEt) 3CO](PF 6) 2 has been isolated and characterized by micro-analyis, electronic, vibrational and voltammetric spectra and conductometric measurements. The aquation of the coordinated CO ligand has been studied. k 1, k −1 and K eq for the reaction trans-[Ru(NH 3) 4P(OEt) 3(H 2O] 2++CO ⇌ trans-[Ru(NH 3) 4P(OEt) 3CO] 2++H 2O are 3.11 M −1 s −1, 2.6×10 −5 s −1 and 1.2×10 5 M −1 at 25 °C, μ=0.10 in NaCF 3CO 2, pH=3.0, respectively. Attempts to prepare trans-[Ru(NH 3) 4PPh 3CO] 2+ are described.
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