Abstract
AbstractIn analogy with the reaction of phenols with very strong super acids, these compounds can be protonated by the weaker super acid trifluoroacetic acid (TFA) and trifluoromethanesulphonic acid (TFS) also giving rise to the formation of OH and/or ring protonated products, which can be identified unambiguously by means of 1HNMR spectroscopy. The same reactions are possible with the deuterated acids TFA‐d and TFS‐d. However, from these reactions, additional information on the proton and deuterium attack at different positions in the phenolic compounds is possible not detectable by the hitherto used non‐deuterated acids. Moreover, the reaction of phenols with these deuterated acids allows the preparation of partially or fully deuterated phenols that are also important as markers in biological application and material chemistry.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
