Abstract
Abstract Experimental potential energy curves for the X1Σ and A1Σ states of BaO have been calculated using the method of Rydberg-Klein-Rees as modified by Kirschner and Watson. The dissociation energy of BaO molecule as estimated using the curve fitting method has been compared with Do (BaO) obtained, using the short-wavelength limit of the chemiluminescence in a controlled reaction of Ba + ×No2 vapors. A critical discussion of the various results has also been given with special reference to the complete sub-shell structure of ‘Ba’ atom.
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