Abstract

An Ising system consisting of triplet ions with a zero-field splitting D and an exchange interaction J between nearest neighbours has been investigated using a molecular field approximation. The behaviour of the susceptibility is discussed. The possibility of first-order phase transitions in magnetic fields is investigated in the case of ferromagnetic exchange ( J > 0). In the limit H → ∞, D → ∞, μH − D = = finite, the system is equivalent to an Ising system of doublet ions with an appropriate value of the exchange interaction in a magnetic field. For large values of D and sufficiently low temperatures, a magnetic field can give rise to one first-order transition, if J > 0, and to two second-order transitions, if J < 0.

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