Abstract
The effect of perturbations on the values of vibration-rotation transition wave-numbers of symmetric-top molecules is investigated, and it is shown that perturbations caused by interactions that can induce so-called ‘forbidden transitions’ yield informations useful to the determination of the ground state K-structure parameters A 0, D 0 K , H 0 K …, even if ‘forbidden transitions’ are not observed. The use of such additional information in the analysis of vibration-rotation spectra is discussed.
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