Abstract

Corrections on the plasma particle balance owing to deviations from the ambipolar Schottky theory are studied. The effects of ion inertia (transition to free fall theory), deviations from quasi-neutrality (transition to free diffusion theory), and stepwise ionization (Spenke theory) are introduced in the form of a numerical correction factor. Also other effects are briefly considered, i.e., gas heating, dependence of ion mobility on temperature and electric field, conversion of He + into He + 2, electron-ion recombination, and the presence of an axial magnetic field. From the plasma balance various characteristics in a diagram of E/ p against pR are derived with the aid of values of the ionization rate that result from computations in which stepwise processes are taken into account. Here E is the strength of the axial electric field along a cylindrical discharge, p is the filling gas pressure, and R is the inner tube radius. The theoretical results show a good agreement with measurements of E in the positive column of a dc discharge in helium for the range of parameters: p = 0.1–2 torr, E/ p = 300–4000 V m -1 torr -1, current I = 0.01–0.4 A, and R = 0.011 m.

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