On the path to catalysts for the low-temperature ammonia synthesis

Abstract

A nontraditional approach to the development of catalysts for low-temperature ammonia synthesis is considered. The approach is characterized by application of catalysts representing heterogeneous analogs of the known homogeneous nitrogen-fixing systems based on transition metal compounds and strong electron donors. The use of this approach led to the development of catalysts that considerably surpass in their activity (at atmospheric pressure) the industrial catalyst for the ammonia synthesis. Some of the developed catalysts are active in the formation of ammonia from dinitrogen and dihidrogen even at 110–150°C. The mechanisms of activation and hydrogenation of dinitrogen over these new catalysts are discussed.