Abstract
The title problem has been investigated in the reaction of 2-decyl bromide with t-C4H9OK/t-C4H9OH system employing 18-crown-6 ether and an "inert" salt (t-C4H9OLi) as mechanistic probes. From olefin-distribution data and a subsidiary kinetic evidence it has been inferred that the investigated effect originates from a concentration-dependent substrate solvation by metal ions in the transition state.
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