On the one-electron theory of crystalline solids in a homogeneous electric field

Abstract

Assuming that the one-electron states of a perfect crystalline solid are known, an approach for the calculation of the one-electron states in the presence of external fields and/or other deviations from the periodic potential of the perfect crystal is suggested. The treatment is based on the Wannier representation and the use of a method for solving some operator non-polynomial differential equations. In the approximation of the one-band Wannier equation an exact solution of the problem for electron states of the crystals in a homogeneous external electric field is given. The results obtained in the tight binding approximation for cubic crystals show that the electron motion along the field is finite and the degree of its finiteness for a given electric field strength is greater, the smaller the width of the initial energy band considered. In the one-band approximation Considered the electron energy spectrum has the character of the Wannier-Stark ladder. It is also shown that an influence of transverse motion on the character of the finite motion along the field appears when a non-additivity in the initial energy band function with respect to the energies of motions parallel and perpendicular to the field direction is present.