Abstract

For three identical spherical atoms in their ground electronic states, it is shown that a knowledge of the partial wave components of the additive non-expanded second-order induction energy allows the non-additive non-expanded second-order Coulomb energy to be calculated for certain interatomic geometries. The results of new partial wave calculations of the non-expanded second-order Coulomb energy are presented for H2 and H3, and are used to discuss the rate of convergence of the appropriate partial wave series. Comparison is made with relevant literature results.

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