Abstract
Configuration interaction calculations of the O1s and C1s core hole states of Cr(CO)6 and C3O2 are described. The increased shielding of the primary core hole states of these molecules compared to those of CO leads to the shift in core ionization energy being determined by final state effects. The intense satellite band in the O1s and C1s spectrum of Cr(CO)6 arises from M(3d)→L(π*) charge transfer transitions involving all six CO ligands.
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