Abstract

Measurements of sound absorption in binary mixtures of gases in which two relaxation processes can occur due to the specific heats of the molecular vibrations, have hitherto been evaluated by using a theory based mainly on gaskinetic considerations. The theory presented here, uses the thermodynamics of irreversible processes as developed byMeixner for sound absorption in fluid systems due to interior reactions of arbitrary kind and number. This treatment permits a concise derivation of the final formulas which are also valid for mixtures of real gases and fluids. According to which set of independent thermodynamical variables for the derivation is used, the final formulas seem to differ considerably. It is pointed out that these differences arise from introducing two types of relaxation times and may be eliminated by means of the relationship between these relaxation times.

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