Abstract

The energy of a graph is defined as the sum of the absolute values of all eigenvalues of the adjacency matrix of the graph. Zhang and Li [F. Zhang, H. Li, On acyclic conjugated molecules with minimal energies, Discrete Appl. Math. 92 (1999) 71–84] determined the first two smallest-energy trees of a fixed size with a perfect matching and showed that the third minimal energy is between two trees. This paper characterizes trees of a fixed size with a perfect matching with third minimal, fourth minimal and fifth minimal energies for n ≥ 86 and third minimal, fourth minimal energies for 14 ≤ n ≤ 84 .

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