Abstract
The mechanism of the chemiluminescent condensation of aniline with butyraldehyde into 3-ethyl-2-propylquinoline catalyzed by LnCl3 · 6H2O (Ln = Tb, Ho) is reported. A likely scheme of the catalytic condensation of aniline with butyraldehyde has been developed by simulation of separate steps of the reaction using chemiluminescence and photoluminescence methods and quantum-chemical calculations of the heats of these steps.
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