Abstract
The state of the art of the problem of matrix stabilization of transition metal ions in unstable oxidation states is surveyed. Basic aspects of the problem concerning the genealogy of matrix systems suitable for the stabilization of this property are classified. Appropriate examples are given, and the data that do not fit the suggested scheme are discussed. This is the case, in particular, for cluster systems stabilized in frozen aqueous solutions, as well as for clusters formed under simpler conditions. The problem of identification of oxidation states in matrix systems, as well as the types of matrices suitable for the stabilization of unstable oxidation states and methods of their stabilization in matrix systems, is considered.
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