Abstract
A hard-core double Yukawa potential is taken as an approximation of the Lennard–Jones (LJ) potential. Using first-order thermodynamic perturbation theory with a hard-sphere fluid as the reference system, the equation of state of the hard-core double Yukawa fluid is derived analytically. Adjusting the hard-core diameter with the Barker and Henderson prescription to account for the repulsive part of the LJ potential, the liquid–vapour coexistence curve of the LJ fluid is computed with such equation of state. The results are compared with simulation data for the LJ fluid and very good agreement is observed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
