Abstract

The explicit expressions for the rate constant kf and kb of a dense system obtained in the preceding paper are investigated numerically. The pair correlation functions representing the spatial correlations are calculated from an associate nonreactive hard sphere system by means of the multicomponent Percus—Yevick equation. The rate constants are found to differ in their dependence on density and time up to an order of magnitude from the corresponding dilute gas value. The time behaviour of kf and kb was found to depend sensitively on a relation between the total volumes of the reactant and product molecules.

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