On the influence of some strong electrolytes on the partitioning of acetic acid to aqueous/organic two-phase systems in the presence of tri- n-octylamine : Part II: Toluene as organic solvent

Abstract

Water-insoluble amines (dissolved in an organic solvent/organic solvent mixture) are often used for the extractive recovery of carboxylic acids from aqueous phases. The basic design of the extraction process requires a thermodynamic framework that should be able to describe the liquid–liquid phase equilibrium not only in the phase forming systems (water + carboxylic acid + organic solvent + reactive extractant), but also when the aqueous feed phase contains additionally small amounts of strong electrolytes. Even small amounts of strong electrolytes might considerably reduce the recovery rate. In part I of this series such a model was presented and discussed for methyl isobutyl ketone as organic solvent and tri- n-octylamine (TnOA) as the chemical extractant. The present part II is to demonstrate that the procedures/methods described for methyl isobutyl ketone as organic solvent can be applied also for other organic solvents. By way of example, here toluene is that organic solvent. New experimental results are reported for the influence of sodium chloride, sodium nitrate, sodium sulfate, sodium acetate and hydrochloric acid on the partitioning of acetic acid to coexisting aqueous/organic liquid phases of the system (water + toluene + tri- n-octylamine) at 25 °C. An extension/adaptation of the previously published thermodynamic framework is successfully applied to describe/predict the new experimental liquid–liquid phase equilibrium data.