Abstract
Cu/SSZ-13 SCR catalysts have been extensively studied in the past decade or so. Hydrothermal stability of these catalysts has been identified as the most important criterion for application. In this perspective, we describe recent atomic-level understanding of their hydrothermal stability. In particular, electron paramagnetic resonance (EPR) is shown to rather accurately quantify isolated Cu(II) ions and CuO clusters in fresh and aged catalysts to demonstrate the remarkable hydrothermal stability for Cu2+ ions located in 6-membered ring windows, and the conversion of [Cu(OH)]+ ions in Chabazite cages to CuO clusters. The hydrothermal stability difference of the two isolated Cu(II) ions is confirmed with DFT simulations and the conversion of [Cu(OH)]+ to CuO is proposed to involve formation, migration and condensation of Cu(OH)2 intermediates. The structural destructive role of CuO clusters is attributed to mesopore formation from their migration, which more severely damages the catalysts than dealumination. Finally, perspectives are given on new strategies for low-temperature NOx removal, rational design and refinement of Cu/SSZ-13, and development of new Cu/zeolite SCR catalysts with even better performance than the state-of-the-art Cu/SSZ-13.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
