Abstract

In the formulas given by the author for the multicenter molecular integrals with an arbitrary s-electron operator F ( s) ( s = 1, 2, …) all the expansion coefficients are expressed through the binomial coefficients. The final results are of a simple structure and are, therefore, especially useful for the calculation of these coefficients for large quantum numbers. By the use of the derived expressions in terms of binomial coefficients multielectron molecular integrals over Slater-type orbitals can be evaluated most efficiently and accurately from the series expansion formulas.

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