Abstract

Linear and non-linear internal friction and the effective Young’s modulus of a Ni50.8Ti49.2 alloy have been studied after different heat treatments, affecting hydrogen content, over wide ranges of temperatures (13–300 K) and strain amplitudes (10−7–10−4) at frequencies near 90 kHz. It has been shown that the contamination of the alloy by hydrogen strongly affects the internal friction and Young’s modulus of the martensitic phase. Presence of hydrogen gives rise to a non-relaxation internal friction maximum due to a competition of two different temperature-dependent processes. The temperature position and height of the maximum depend strongly on the hydrogen content. We conclude that many of the internal friction peaks, reported earlier for differently treated Ni-Ti-based alloys, had the same origin as the present maximum.

Highlights

  • Ni-Ti-based alloys represent the most important family of shape memory alloys for applications.Anelastic properties of Ni-Ti-based alloys have attracted considerable attention, both for the microstructural characterization of the alloys and for their application as high-damping materials [1].the bulk of studies have been performed in the temperature range around phase transformation temperatures

  • A variety of maxima were reported in the temperature spectra of the internal friction (IF)

  • One sample was tested in the as-received (AR) state. Another one was subjected to a sequence of heat treatments: (1) vacuum quenching (VQ); (2) water quenching (WQ); and, (3) four consecutive vacuum annealings (VA1–VA4)

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Summary

Introduction

Ni-Ti-based alloys represent the most important family of shape memory alloys for applications.Anelastic properties of Ni-Ti-based alloys have attracted considerable attention, both for the microstructural characterization of the alloys and for their application as high-damping materials [1].the bulk of studies have been performed in the temperature range around phase transformation temperatures. Ni-Ti-based alloys represent the most important family of shape memory alloys for applications. Anelastic properties of Ni-Ti-based alloys have attracted considerable attention, both for the microstructural characterization of the alloys and for their application as high-damping materials [1]. Anelastic properties of martensitic phases have attracted less attention, especially at low temperatures. The so-called ‘200 K’ relaxation IF peak was first observed by Hasiguti and Iwasaki [2] and by many other researchers [1]. It has been attributed to an interaction of twin boundaries with hydrogen [3,4]. Another IF peak around 100 K was reported and ascribed to a dislocation relaxation by Tirbonod and Koshimizu [5].

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