Abstract
AbstractThe solution properties of unfractionated styrene/methyl methacrylate copolymers were investigated over the entire range of copolymer composition. The Mark‐Houwink‐Sakurada constants Kη, and aη of the copolymers, as well as the constants KΘ and B′ from the Stockmayer‐Fixman procedure, related to the unperturbed chain dimensions and to the excluded volume, respectively, seem simply related to those of the parent homopolymers through some composition variables. In most cases, however, equations must be employed which have to be fitted to the experimental data, in order to evaluate parameters which are not otherwise predictable.
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