On the development of relativistic distorted wave approximation for the energies and collision dynamics of atoms or ions subjected to the outside plasma

Abstract

In this manuscript, we present the development of a relativistic distorted wave method for determining the energies and collision dynamics of plasma-immersed atoms or ions. The methodology is based on the Dirac–Coulomb Hamiltonian, in which contributions from relativity and higher order effects, such as quantum electrodynamics and Breit interaction, are incorporated. The key element in this method is that a modified Debye–Hückel approximation is employed to represent the effect of plasma screening. In order to correctly describe the (bound and continuous state) wave functions, a self-consistent field calculation incorporating the shielding potential is performed within the fully relativistic framework. The particle interaction within the scattering matrix element of the excitation process is described by the shielded Coulomb interaction. The present technique is illustrated by calculations of energy, line shift, transition probability, electron-impact excitation/ionization cross section, and photoionization cross section of a few-electron system confined in plasma environments. The present model is tested and validated against a number of known cases (simulations are made for the He-like Al11+ ion) in the literatures. Numerical results demonstrate that the modifications to the Coulomb potential proposed in the spatial and temporal criteria of the Debye–Hückel approximation allow us to improve the theoretical description of the plasma shielding and thus the dynamical processes in dense plasmas. Comparisons of our computational predictions and the recent experimental measurements are performed. The current work not only has far-reaching implications for our understanding of the dense plasma screening, but also has potential applications in fusion, laboratory astrophysics, and related disciplines.