Abstract
We report on photoionization measurements of three Ce 3+ doped chlorides: Cs 3LuCl 6, Cs 2LiLuCl 6 and Cs 2LiYCl 6. These chlorides are hygroscopic and must be kept hermetically sealed in quartz vials, complicating the use of standard techniques to determine electron transfer processes. Thus, a solely optical technique, based on thermoluminescence excitation spectroscopy, is applied to detect the photoionization energies of Ce 3+ in the three compounds.
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