Abstract

The nullity of a graph G, denoted by η(G), is the multiplicity of 0 in the spectrum of G. Nullity of a (molecular) graph (e.g., a bipartite graph corresponding to an alternant hydrocarbon) has important applications in quantum chemistry and Hückel molecular orbital (HMO) theory. A famous problem, posed by Collatz and Sinogowitz in 1957, asks to characterize all graphs with positive nullity. Clearly, detA(G)=0 if and only if η(G)>0. So, examining the determinant of a graph is a way to attack this problem. For a graph G, we define the matching core of G to be the graph obtained from G by successively deleting each pendant vertex along with its neighbour. In this paper, we show that the determinant of a graph G with all cycle lengths divisible by four (e.g., the 1-subdivision of a bipartite graph), is 0 or (−1)|V(G)|/2. Furthermore, the determinant is 0 if and only if the matching core of G is nonempty.

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