Abstract

Ionic thermal currents (ITC) and electron paramagnetic resonance (EPR) experiments were performed to identify the different types of defects existing in Ca 1− x Gd x F 2+ x solid solutions, with x = 0.05% and 0.1%. The results show the presence of cubic and tetragonal centers together with cluster-associated relaxation peaks. Successive ITC runs were performed in order to duplicate recent results in which the ITC peaks were reported to change significantly in intensity, position and even in number after the application of an electric field. The results reported here show that there are no changes after successive ITC runs, neither in the ITC nor in the EPR spectra obtained from these crystals. Moreover, the absence of trigonal centers in these oxygen-free crystals is once more confirmed and the equilibration among the two dipolar types ascribed to the influence of the polarizing field is thus discarded in the CaF 2:Gd 3+ crystals.

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