Abstract
Abstract A chiral disilanyl radical produced from (−)-1-methyl-1,2,2,2-tetraphenyldisilane, [α]D-8.9°, undergoes chlorine abstraction to give the corresponding chlorodisilane with retention of configuration but in low optical yield, contrary to the case of the previously-reported chiral monosilyl radical. Factors influential on the stereochemical course on these radicals are discussed.
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