Abstract
The critical lines of binary mixtures of conformal fluids are calculated on the basis of the one-fluid Van der Waals theory. The conditions for the existence of the gas/gas equilibrium of the first and second type are shown and discussed. The analytical expressions for partial derivatives of Gibbs free energy with respect to concentration, up to the third order, are given in the appendix.
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More From: Journal of Research of the National Bureau of Standards
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