Abstract

Abstract Infrared and Raman spectra of liquid formamide and its deuterated analog were examined. Depolarization ratio measurements in the NH 2 stretching region indicated that the previous assignment of the NH 2 band was erroneous. The re-interpretation of the liquid formamide vibrational spectra is presented. The i.r. spectra of dilute formamide solutions in various organic bases gave additional support for the proposed assignment.

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