Abstract

A comparative survey is made of the neutron and light scattering techniques as applied to structural investigations in the vicinity of critical points in fluids. For neutron scattering as applied to fluctuations in binary mixtures, some criteria for a good contrast in order to optimize the scattering parameters such as the isotopic composition or the concentration are considered. This leads us to show how to write the partial structure factors in binary mixtures in order to remove the coupling between concentration and density fluctuations artificially introduced bv Bhatia and Thornton when the components are of different size. Finally, the amplitudes of the concentration fluctuations near a critical point are discussed.

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