Abstract
Alkyl radical formation in halocarbon matrices containing the parent radical cation has been studied for various alkyl-substituted cyclohexanes. Contrary to the reaction mechanism suggested earlier, no direct relationship was found between the locations of high hydrogen spin density in the cation and the site of the π-type alkyl radicals which are formed. Among the cis and trans isomers of di- and tri-methylcyclohexanes, tertiary alkyl radicals were found to be always formed most preferentially whenever the corresponding solute molecule has at least one axial methyl group on the chair conformation. The other isomers gave secondary alkyl radicals with the site in the ring structure.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
