Abstract
While photosynthetically evolved O2 has been repeatedly shown to have nearly the same oxygen isotope composition as source water so that there is no corresponding 16O/18O isotope effect, some recent 18O-enrichment studies suggest that a large isotope effect may occur, thus feeding a debate in the literature. Here, the classical theory of isotope effects was applied to show that a very small isotope effect is indeed expected during O2 production. Explanations of the conflicting results are briefly discussed.
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