On-site passive flux sampler measurement of emission rates of carbonyls and VOCs from multiple indoor sources

Abstract

In indoor environments with high levels of air pollution, it is desirable to remove major sources of emissions to improve air quality. In order to identify the emission sources that contribute most to the concentrations of indoor air pollutants, we used passive flux samplers (PFSs) to measure emission rates of carbonyl compounds and volatile organic compounds (VOCs) from many of the building materials and furnishings present in a room in a reinforced concrete building in Tokyo, Japan. The emission flux of formaldehyde from a desk was high (125 μg/m 2/h), whereas fluxes from a door and flooring were low (21.5 and 16.5 μg/m 2/h, respectively). The emission fluxes of toluene from the ceiling and the carpet were high (80.0 and 72.3 μg/m 2/h, respectively), whereas that from the flooring was low (9.09 μg/m 2/h). The indoor and outdoor concentrations of formaldehyde were 61.5 and 8.64 μg/m 3, respectively, and those of toluene were 43.2 and 17.5 μg/m 3, respectively. The air exchange rate of the room as measured by the perfluorocarbon tracer (PFT) method was 1.84/h. Taking into consideration the area of the emission sources, the carpet, ceiling, and walls were identified as the principal emission sources, contributing 24%, 20%, and 22% of the formaldehyde, respectively, and 22%, 27%, and 14% of the toluene, respectively, assuming that the emission rate from every major emission sources could be measured. In contrast, the door, the flooring, and the desk contributed little to the indoor levels of formaldehyde (1.0%, 0.54%, and 4.1%, respectively) and toluene (2.2%, 0.31%, and 0.85%, respectively).