On-road tailpipe characterization of exhaust ammonia emissions from in-use light-duty gasoline motor vehicles

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A Portable Emissions Monitoring System (PEMS) has been used to estimate ammonia emission rates from a representative fleet of 47 in-use light-duty gasoline motor vehicles over 145 on-road Real Driving Emissions (RDE) tests. The PEMS modules were carried onboard the tested vehicles and were wired such that their ceramic exhaust emission sensors were mounted directly in the tailpipe. The on-road RDE tests were conducted over an urban testing route that included residential and highway roads, uphill and downhill road segments, stop signs, traffic lights, and a school zone with a reduced speed limit. The entire vehicle test sample had an average ammonia emission rate of 114.7 mg/mile ±135.3 (StD). This would yield an estimated 2909 metric tons per year of NH3 emissions from the Wasatch fleet on-road gasoline motor vehicles. Old vehicles with aged Three-Way Catalyst (TWC) converters had higher NH3 emissions rates than newer vehicles with newer TWC converters. For instance, Tier 0, Tier I, NLEV, Tier II and Tier III vehicles had average emission rates of 563.1, 177.8, 213.6, 94.4 and 18.9 mg/mile, respectively. Carbon monoxide, and nitrogen oxides had a strong correlation with ammonia emission rates, with r ≥ 0.70. A Moderate correlation was found with vehicles’ mileage (r = 0.6), model year (r = −0.5), engine displacement (r = 0.4), and number of cylinders (r = 0.4). The outcomes highlight vehicle contributions to the atmospheric NH3 inventory and the impact of vehicle characteristics and ammonia precursor concentrations on ammonia emission rates from gasoline vehicles.