Abstract
The Hartree-Fock approximation is applied to the momentum space representation of a relativistic many-electron Hamiltonian which, in contrast to the Dirac-Coulomb Hamiltonian, possesses bound-state solutions. Using the linear-expansion technique new analytical (or matrix) relativistic Hartree-Fock equations are obtained which may provide a starting point for improved molecular calculations.
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More From: Journal of Physics B: Atomic and Molecular Physics
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