On perturbation theory in statistical mechanics

Abstract

We discuss the application of perturbation theory to statistical mechanics both in the operator form of Schwinger and in the scalar form as a sum over states. We briefly consider and compare the use of variational parameters in both approaches. By means of a simple model we show that Schwinger perturbation theory might fail when the eigenfunctions satisfy Dirichlet boundary conditions. On the other hand, the sum over states gives accurate results.