On Nanobubble Dynamics under an Oscillating Pressure Field during Salting-out Effects and Its DLVO Potential

Abstract

We have investigated the origin, stability, and nanobubble dynamics under an oscillating pressure field followed by the salting-out effects. The higher solubility ratio (salting-out parameter) of the dissolved gases and pure solvent nucleates nanobubbles during the salting-out effect, and the oscillating pressure field enhances the nanobubble density further as solubility varies linearly with gas pressure by Henry's law. A novel method for refractive index estimation is developed to differentiate nanobubbles and nanoparticles based on the scattering intensity of light. The electromagnetic wave equations have been numerically solved and compared with the Mie scattering theory. The scattering cross-section of the nanobubbles was estimated to be smaller than the nanoparticles. The DLVO potentials of the nanobubbles predict the stable colloidal system. The zeta potential of nanobubbles varied by generating nanobubbles in different salt solutions, and it is characterized by particle tracking, dynamic light scattering, and cryo-TEM. The size of nanobubbles in salt solutions was reported to be higher than that in pure water. The novel mechanical stability model is proposed by considering both ionic cloud and electrostatic pressure at the charged interface. The ionic cloud pressure is derived by electric flux balance, and it is found to be twice the electrostatic pressure. The mechanical stability model for a single nanobubble predicts the existence of stable nanobubbles in the stability map.