Abstract
AbstractIn nature trees may have many different forms and so have all natural branched structures. Differences in branched architectures of synthetic polymers can only be explained by kinetics. We compare radical polymerization of low density Polyethylene (PE) and PE polymerization with Constrained Geometry Catalyst (CGC) metallocene. The architectures generated by our synthesis algorithms revealed marked differences between the two PE‐systems. Metallocene‐PE turned out to be more comb‐like. This could partially be explained by analyzing growth patterns of the two PE types as incorporated in the architecture synthesis algorithms.
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