Abstract
Potential curves for theB andX states of I2, NS and PS have been obtained by Rydberg-Klein-Rees (RKR) method. From these RKR potentials, Franck-Condon factors (FCFs) lot the above band systems have been calculated using the best available molecular constants, tested for accuracy on the electronic transition moment (ETM)-r-centroid curve in the case of I2 and used in the study of observed abnormal intensity distribution in some bands of NS. A brief outline of the method used in the calculations of the FCFs is given.
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