On flow-enhanced crystallization in fiber spinning: Asymptotically justified boundary conditions for numerics of a stiff viscoelastic two-phase model

Abstract

For flow-enhanced crystallization in fiber spinning, the viscoelastic two-phase fiber models by Doufas et al. (2000) and Shrikhande et al. (2006) are state of the art. However, the boundary conditions associated to the onset of crystallization are still under discussion, as their choice might cause artificial boundary layers and numerical difficulties. In this paper we show that the model class of ordinary differential equations is singularly perturbed in a small parameter belonging to the semi-crystalline relaxation time and derive asymptotically justified boundary conditions. Their effect on the overall solution behavior is restricted to a small region near the onset of crystallization. But their impact on the performance of the numerical solvers is huge, since artificial layering, ambiguities and parameter tunings are avoided. The numerics becomes fast and robust and opens the field for simulation-based process design and material optimization.