Abstract

AbstractNitrosyl radioruthenium trichloride and radioruthenium hydroxytrichloride carrier free were prepared. Solvent extraction studies of both compounds in HCl and NaCl aqueous solutions lead to the conclusion that change in Ru‐valence state from II to IV decrease the extractability of the element by Tri‐n‐butyl phosphate (“TBP”) seriously. A probable interpretation is stated. It was also shown that the extracting power of TBP increases with dehydration and decreases with acidolysis by HCl aqueous solutions. Data are represented and discussed.

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