Abstract

This paper is concerned with the global existence, uniqueness and homogenization of degenerate partial differential equations with integral conditions arising from coupled transport processes and chemical reactions in three-dimensional highly heterogeneous porous media. Existence of global weak solutions of the microscale problem is proved by means of semidiscretization in time deriving a priori estimates for discrete approximations needed for proofs of existence and convergence theorems. It is further shown that the solution of the microscale problem is two-scale convergent to that of the upscaled problem as the scale parameter goes to zero. In particular, we focus our efforts on the contribution of the so-called first order correctors in periodic homogenization. Finally, under additional assumptions, we consider the problem of the uniqueness of the solution to the homogenized problem.

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