Abstract

The electrochemical behaviour of Zn has been investigated in DMSO, DMF and AN by potentiostatic and voltammetric methods. The values of α n and β n equal to 0.5 and 1 show that the charge-discharge of Zn 2+ in these solvents proceeds as a two-step reaction. The values of apparent exchange current densities depend on the employed measurement techniques. The assumption about the passivation of Zn electrode by the products of secondary chemical reaction has been formulated.

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